Conceptual geological models of industrial and mining megasites ire all essential task of groundwater investigations as well as environmental risk assessment studies. Therefore, the conceptualization process of the structural geological model has depended oil the development of,I set of 2D cross-sections to portray a 3D picture of groundwater flow. This attempt always includes some simplifications that require, only to some extent, the true 3D situation of heterogeneous aquifers. Consequently, the modelled predictions of the path flow and transport conditions of contaminated groundwater are not satisfying in terms of a flow-path and risk based modelling approach. A more structured approach to develop the hydrogeological framework for the conceptual model is advocated, using different 3D geological modelling software packages to assemble the data, working in three dimensions and using this platform for subsequent groundwater flow modelling. Attention is given to the capability of different 3D modelling approaches, indicated by geostatistically based versus constructive cross-section based interpolations of complex sedimentary successions, that are compared in their results and suitability for subsequent hydrogeological modelling requirements. The paper describes the results, in high-resolution 3D modelling, of the complex geological environment of the Bitterfeld/Wolfen megasite in the eastern part of Germany. Identification, assessment, and remediation of large-scale groundwater contamination require a detailed knowledge of the heterogeneous geological structure to predict the fate and pathways of contaminants and their potential interaction with, e.g., surface water. An area of 16 kill 2 of the model area of the Bitterfeld/Wolfen area was chosen to transfer the complex structural geological setting. The subsurface geology could be assigned to 31 lithostratigraphic units and depicted using a 10 x 10m GIS grid. This constructive and knowledge-driven 3D modelling allows the prediction of vertical and horizontal Sections, Visualization purposes, volumetric calculations of distinct sedimentary units, GIS applications, and the use of the detailed digital information within the subsequent flow and transport groundwater modelling. The high-resolution digital 3D model improves the hydrogeological modelling results. It is considered a basic requirement for groundwater modelling and investigations on environmental risk and impact assessment by fate and pathway exposure route analysis of the complex geological and groundwater situations. (C) 2007 Elsevier Ltd. All rights reserved.